What chemical process results in soapy or stale flavors due to fat breakdown by lipolytic enzymes?
Answer
Rancidity
Rancidity describes the spoilage state in high-fat foods, like oils or nuts, characterized by the development of soapy, bitter, or stale flavors and odors. This chemical deterioration is specifically caused by the action of lipolytic enzymes, which break down the stored fats (lipids) into free fatty acids. This process is a form of chemical spoilage occurring within the food matrix itself. The Maillard reaction involves sugars and amino acids leading to browning, oxidation affects vitamins and causes paint-like off-flavors, and starch retrogradation is the physical process leading to staling in baked goods.

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