What causes staling in baked goods during physical deterioration?

Answer

Starch molecules retrograde

Staling in baked goods is categorized as a physical spoilage phenomenon, distinct from microbial activity or significant chemical reactions. This change in texture, resulting in the product becoming hard, occurs because the starch molecules within the baked structure undergo a process called retrogradation. This retrogradation involves the reordering and crystallization of the starch polymers, leading to a loss of the soft, pliable texture characteristic of fresh bread. Moisture sublimation is responsible for freezer burn, lipid degradation leads to rancidity (chemical spoilage), and alcohol/CO2 production is a byproduct of yeast fermentation (microbial spoilage).

What causes staling in baked goods during physical deterioration?
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